Does Titanium Rust?

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Titanium does not rust like iron (i.e., it doesn’t form red iron oxide), but it does oxidize under certain conditions, forming an ultra-thin protective oxide layer. Here’s the full breakdown:

titanium materials

1. Why Titanium "Doesn’t Rust"

Self-Healing Oxide Layer: When exposed to air, titanium instantly forms a 5-10 nm thick titanium dioxide (TiO₂) layer, which:

It is dense and chemically inert

Self-repairs if damaged (even scratches heal)

Completely prevents further corrosion

Comparison with Other Metals:

Metal Oxide Layer Behavior "Rusts"?
Titanium Dense, stable ❌ No rust
Iron Porous, flaky ✅ Rusts (Fe₂O₃)
Aluminum Stable but wears ❌ No rust (but oxidizes & darkens)

2. Titanium’s Performance in Extreme Environments

Seawater/Saltwater: Fully resistant, corrosion rate <0.001 mm/year (1/100th of stainless steel)

Strong Acids/Alkalies:

Resists nitric acid, dilute sulfuric acid (<10%)

Vulnerable to hydrofluoric acid & hot concentrated sulfuric acid (dissolves the oxide layer)

High-Temperature Oxidation:

Below 600°C: Oxide layer remains stable

Above 800°C: Gradually thickens (darkens but doesn’t flake)

Real-World Case: Titanium deep-sea submersible pressure hulls show zero corrosion after 30 years underwater.

3. Why Titanium is Called the "Metal That Never Corrodes"

Natural Passivation: The oxide layer is more corrosion-resistant than the base metal

No Galvanic Corrosion: Doesn’t accelerate corrosion when in contact with other metals

Biocompatibility: Used in medical implants (e.g., bone screws) for 50+ years without degradation

4. Rare Exceptions & Precautions

Hydrogen Embrittlement: In high-pressure hydrogen environments, titanium can absorb hydrogen and become brittle (use low-hydrogen-grade titanium)
Mechanical Wear: Continuous friction may damage the oxide layer (requires surface hardening)

Final Verdict

Titanium does not rust in most environments—its oxide layer is even more stable than gold. However, in the presence of hydrofluoric acid or hot concentrated alkalis, special alloy selection is required.

Need corrosion data for your application? Share your operating conditions, and we’ll recommend the best titanium grade for your needs.

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Email: linhui@lhtitanium.com

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